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Controlled Release of Biologically Active Agents", Vol. 47 of Advances in Experimental Medicine and Biology, Plenum Press, New York, 1974. 8. Cardarelli, N. , "Controlled Release Pesticide Sym­ posium", The University of Akron, 1974. 9. Harris, F. , "Proceedings 1975 International Con­ trolled Release Pesticide Symposium", Wright State University, Dayton, Ohio, 1975. 10. , Parkridge, N. , 1969. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1977. 2. ROGERS Permeability through a Polymer Matrix 29 11.

S o i l a n a l y s i s confirmed that a f t e r 7 days, 26% of the a p p l i e d e m u l s i f i a b l e concentrate and 51% of the microencapsulated chlorpropham remained i n the t a r g e t area. A major b e n e f i t that c o n t r o l l e d r e l e a s e technology can b r i n g t o weed c o n t r o l i s t o expand h e r b i c i d e s e l e c t i v i t y t o a d d i t i o n a l crops. As i l l u s t r a t e d i n Figure 3, based on a suggestion by Dawson (1976), the amount o f h e r b i c i d e r e q u i r e d t o c o n t r o l weeds i n crop A may i n j u r e crop B.

Environmental Impact of Polymers Before c o n s i d e r i n g the environmental impact of CR p e s t i c i d e f o r m u l a t i o n s , i t i s importan m a t e r i a l s , or the s o - c a l l e d " i n e r t s , " which make up the bulk of these types of f o r m u l a t i o n s . Table IV i s a l i s t of s i g n i f i c a n t polymers that were chosen f o r c l o s e r i n v e s t i g a t i o n . TABLE IV CONTROLLED RELEASE MATERIALS Rubber Natural Synthetic Ethylene - Propylene Polymer C e l l u l o s i c Materials P o l y i s o b u t y l e n e - Butyl Rubber Styrene - Butadiene Copolymer P o l y a c r y l o n i t r i 1 es Polyacrylates Polyesters Polyamides Polyethylene Polyvinyl Chloride Chloroprene Polymer Polyurethanes Ci s Polybutadiene Acetal Copolymer Others: S i l i c o n Rubber Polyacrylamides Hydrin Rubber Microporous P l a s t i c Sheet A d i r e c t quotation by C a r d a r e l l i and Walker i n t h e i r f i n a l r e p o r t to the EPA on the Development of R e g i s t r a t i o n C r i t e r i a f o r CR P e s t i c i d e Formulations, sums up t h e i r views on the e n v i r o n mental impact from the use of CR p e s t i c i d e products : " I t should be recognized that the polymeric material must degrade i n some fashion before there can be any environmental impact i n the c h e m i c a l , biochemical or b i o l o g i c a l sense.

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Amateur Photographer, 17 December 2011 by Damien Demolder

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